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dc.contributor.authorFuertes, I.
dc.contributor.authorGómez Lavín, Sonia 
dc.contributor.authorElizalde Ruiz De Larramendi, Maria Puy
dc.contributor.authorUrtiaga Mendia, Ana María 
dc.contributor.otherUniversidad de Cantabriaes_ES
dc.description.abstractLandfill leachates have been recognized as significant secondary sources of poly- and perfluoroalkyl substances (PFASs). This study presents data on the occurrence and concentration of 11 perfluoroalkyl carboxylates (PFCAs) and 5 perfluoroalkyl sulfonates (PFSAs) in leachates from 4 municipal solid waste landfill sites located across northern Spain. To the best of our knowledge, this is the first report of the presence of PFASs in Spanish landfill leachates. Two of the landfill sites applied on-site treatment using membrane bioreactors (MBR), and its effect on PFASs occurrence is also reported. Total PFASs (∑PFASs) in raw leachates reached 1378.9 ng/L, while in treated samples ∑PFASs was approximately two-fold (3162.3 ng/L). PFCAs accounted for the majority of the detected PFASs and perfluorooctanoic acid (PFOA) was the dominant compound in raw leachates (42.6%), followed by shorter chain PFHxA (30.1%), PFPeA and PFBA. The age of the sites might explain the PFASs pattern found in raw leachates as all of them were stabilized leachates. However, PFASs profile was different in treated samples where the most abundant compound was PFHxA (26.5%), followed by linear perfluorobutane sulfonate (L-PFBS) (18.7%) and PFOA (17.7%). The overall increase of the PFASs content as well as the change in the PFASs profile after the MBR treatment, could be explained by the possible degradation of PFASs precursors such as fluorotelomer alcohols or fluorotelomer sulfonates. Using the volume of leachates generated in the landfill sites, that served 1.8 million people, the discharge of 16 ∑PFASs contained in the landfill leachates was estimated as 1209 g/year.es_ES
dc.description.sponsorshipThe authors thank financial support from the Spanish Ministry of Economy and Competitiveness (Project CTM2013-44081-R).es_ES
dc.format.extent43 p.es_ES
dc.rights© 2017, Elsevier. Licensed under the Creative Commons Reconocimiento-NoComercial-SinObraDerivadaes_ES
dc.sourceChemosphere, 2017, 168, 399–407es_ES
dc.subject.otherPerfluoroalkyl substances (PFAS)es_ES
dc.subject.otherLandfill leachatees_ES
dc.subject.otherPerfluorooctanoic acid (PFOA)es_ES
dc.subject.otherPerfluoroalkyl carboxylateses_ES
dc.subject.otherPerfluoroalkyl sulfonateses_ES
dc.titlePerfluorinated alkyl substances (PFASs) in northern Spain municipal solid waste landfill leachateses_ES

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© 2017, Elsevier. Licensed under the Creative Commons Reconocimiento-NoComercial-SinObraDerivadaExcept where otherwise noted, this item's license is described as © 2017, Elsevier. Licensed under the Creative Commons Reconocimiento-NoComercial-SinObraDerivada