Investigation of the degradation of a wood pulp-cotton presspaper in different biodegradable oils

Abstract

New insulating materials, as biodegradable oils and upgraded paper, need to be investigated. In this paper, the ageing of a wood pulp - cotton presspaper is studied. Solid insulation is impregnated and aged with three different fluids: a mineral oil and two vegetable oils, from sunflower and soybean. Both oils and paper were dried before the ageing process, which was carried out at 150°C for 732 hours in iron vessels. Degradation of oils is analysed through the measurement of their breakdown voltage, dielectric dissipation factor (tan δ), resistivity, moisture content and acidity. Deterioration of presspaper is quantified by its polymerization degree (DP), moisture content and dielectric dissipation factor. Results showed that the dielectric properties of oils are negatively affected by the ageing, since the breakdown voltage and resistivity were reduced, whereas the dissipation factor increased. Also, acidity increased, especially in the vegetable oils. In the case of the solid insulation, its tanδ increased with the ageing, despite the reduction of its moisture content. DP was reduced, reaching the end-of-life criteria (DP<200) in the ageing with mineral oil (134) whereas it remained at higher values for the sunflower (206) and soybean (216) oils.