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Copper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicals

dc.contributor.authorLandaluce, Nerea
dc.contributor.authorPerfecto Irigaray, Maite
dc.contributor.authorAlbo Sánchez, Jonathan 
dc.contributor.authorBeobide Pacheco, Garikoitz
dc.contributor.authorCastillo García, Óscar
dc.contributor.authorIrabien Gulías, Ángel 
dc.contributor.authorLuque Arrebola, Antonio
dc.contributor.authorSan José Méndez, Alba
dc.contributor.authorPlatero Prats, Ana Eva
dc.contributor.authorPérez Yáñez, Sonia
dc.contributor.otherUniversidad de Cantabriaes_ES
dc.date.accessioned2022-11-23T14:14:01Z
dc.date.available2022-11-23T14:14:01Z
dc.date.issued2022-05-20
dc.identifier.issn2045-2322
dc.identifier.otherPID2019-108028GB-C21es_ES
dc.identifier.otherPID2019-104050RA-I00es_ES
dc.identifier.otherRTI2018-096138-A-I00es_ES
dc.identifier.urihttps://hdl.handle.net/10902/26600
dc.description.abstractThe doping of zirconium based EHU-30 and EHU-30-NH2 metal-organic frameworks with copper(II) yielded a homogeneous distribution of the dopant with a copper/zirconium ratio of 0.04-0.05. The doping mechanism is analysed by chemical analysis, microstructural analysis and pair distribution function (PDF) analysis of synchrotron total scattering data in order to get deeper insight into the local structure. According to these data, the Cu(II) atoms are assembled within the secondary building unit by a transmetalation reaction, contrarily to UiO-66 series in which the post-synthetic metalation of the MOF takes place through chemical anchorage. The resulting materials doubled the overall performance of the parent compounds for the CO2 electroreduction, while retained stable the performance during continuous transformation reaction.es_ES
dc.description.sponsorshipFinancial support from the European Union Next Generation (EUR2020-112294), the Spanish Ministry of Science and Innovation (PID2019-108028GB-C21, PID2019-104050RA-I00 and RTI2018-096138-A-I00) and Basque Government (IT1291-19) is acknowledged. M.P.-I. thanks a predoctoral fellowship from UPV/EHU (PIF 18/175). A.E.P.-P. and J.A. thank the financial support from the Spanish Ministry of Science and Innovation (“María de Maeztu” Programme for Units of Excellence in R&D: CEX2018-000805-M; Ramón y Cajal fellowships: RYC2018-024328-I and RYC-2015-17080). We acknowledge DESY (Hamburg, Germany), a member of the Helmholtz Association HGF, for the provision of experimental facilities. Parts of this research were carried out at PETRA III beamline P02.1.es_ES
dc.format.extent7 p.es_ES
dc.language.isoenges_ES
dc.publisherNature Publishing Groupes_ES
dc.rightsAttribution 4.0 Internationales_ES
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.sourceScientific Reports, 2022, 12, 8505es_ES
dc.titleCopper(II) invigorated EHU-30 for continuous electroreduction of CO2 into value-added chemicalses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.relation.publisherVersionhttps://doi.org/10.1038/s41598-022-11846-wes_ES
dc.rights.accessRightsopenAccesses_ES
dc.identifier.DOI10.1038/s41598-022-11846-w
dc.type.versionpublishedVersiones_ES


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