Consequences of conformational flexibility in hydrogen-bond-driven self-assembly processes

Berrocal, José Augusto; Di Meo, Florent; García Iglesias, Miguel; Gosens, Ronald P. J.; Meijer, Egbert Willem; Linares, Mathieu; Palmans, Anja R. A.

doi:10.1039/C6CC05593A

Ver/Abrir

ConsequencesofConfor ... (1.860Mb)

Identificadores

URI: http://hdl.handle.net/10902/20117

DOI: 10.1039/C6CC05593A

ISSN: 1359-7345

ISSN: 1364-548X

Fecha

2016-09-18

Derechos

Atribución 3.0 España

Publicado en

Chemical Communications, 2016, 52(72), 10870-10873

Editorial

Royal Society of Chemistry

Enlace a la publicación

https://doi.org/10.1039/C6CC05593A

Resumen/Abstract

We report the synthesis and self-assembly of chiral, conformationally flexible C3-symmetrical trisamides. A strong Cotton effect is observed for the supramolecular polymers in linear alkanes but not in cyclic alkanes. MD simulations suggest 2:1 conformations of the amides within the aggregates in both types of solvents, but a chiral bias in only linear alkanes.

Colecciones a las que pertenece

D51 Artículos [155]

Excepto si se señala otra cosa, la licencia del ítem se describe como Atribución 3.0 España