@article{10902/35473,
year = {2024},
month = {10},
url = {https://hdl.handle.net/10902/35473},
abstract = {Environmental concerns surrounding petrochemical-based materials are constantly increasing and they are
pushing the industry to find renewable sources and sustainable solutions. Recent years have also witnessed a
focus on the development of multifunctional and metamaterials such as auxetic structures. This work describes
the manufacturing of castor-oil-biobased polyurethane foams and their use as platforms to make doublearrowhead auxetic (DAH) metamaterials via laser ablation. A microstructural analysis is conducted on the biobased foam, revealing a micro-cellular structure formed by rounded and closed cells. The proposed DAH structures are innovative because they possess two different micro and macro cellular scales. The effects of the geometric parameters (angles) of the macro-cells of the DAH structures on the equivalent density, elastic modulus, yield stress, ultimate stress, modulus of toughness, and Poisson ratio are investigated. Configurations with a lower unit cell a angle of 45º exhibited improved properties, including the maximum tensile performance (yield stress of 33.2 kPa, ultimate stress of 38.9 kPa, and modulus of toughness of 10.1 mJ/mm3) and the lower negative value for the Poisson ratio (-0.16), although with a higher density (70 kg/m3). In contrast, DAH structures made with a 70º a angle resulted in a reduced equivalent density of 48 kg/m3 and increased specific strength (0.61 kPa.m3/kg). In terms of specific stiffness, the 45º a DAH structures outperform the other configurations, with a specific elastic modulus close to 10 kPa.m3/kg.},
organization = {The authors acknowledge the support of the Brazilian Research Agencies, including CNPq (PQ- 305553/2023-2) and FAPEMIG; the Spanish Research Agency, Fundación Carolina (C.2023); and the European Research Council (ERC-2020-AdG 101020715 NEUROMETA) for the financial support provided. The authors would also like to extend their thanks to Imperveg® (Brazil) for providing the castor oil polymer.},
publisher = {Elsevier},
publisher = {Industrial Crops and Products, 2024, 218, 118828},
title = {Double-arrowhead castor-oil biobased polyurethane foam metamaterials},
author = {de Magalhães Santos, Gabriel Bernardo and Fernandes Soares, Luiza and Baeza Campuzano, Alberto Jorge and da Silva, Rodrigo José and Thomas García, Carlos and Panzera, Túlio Hallak and Scarpa, Fabrizio},
}