@article{10902/32987, year = {2018}, month = {8}, url = {https://hdl.handle.net/10902/32987}, abstract = {Resistively heated diamond-anvil cells have been used together with synchrotron x-ray diffraction to investigate the phase diagram of calcium up to 50 GPa and 800 K. The phase boundaries between the Ca-I (fcc), Ca-II (bcc), and Ca-III (simple cubic, sc) phases have been determined at these pressure-temperature conditions, and the ambient temperature equation of state has been generated. The equation of state parameters at ambient temperature have been determined from the experimental compression curve of the observed phases by using third-order Birch-Murnaghan and Vinet equations. A thermal equation of state was also determined for Ca-I and Ca-II by combining the room-temperature Birch-Murnaghan equation of state with a Berman-type thermal expansion model.}, organization = {Part of the research was supported by the Spanish Government MINECO under Grants No. MAT2016-75586- C4-1/4P and No. MAT2015-71070-REDC.}, publisher = {American Physical Society}, publisher = {Physical Review Materials, 2018, 2(8), 083608}, title = {Phase diagram of calcium at high pressure and high temperature}, author = {Anzellini, S. and Errandonea, Daniel and MacLeod, Simon G. and Botella Vives, P. and Daisenberger, D. and De'Ath, J. M. and González Platas, J. and Ibañez, J. and McMahon, M. I. and Munro, K. A. and Popescu, Catalin and Ruiz Fuertes, Javier and Wilson, C. W.}, }