@article{10902/32626,
year = {2016},
url = {https://hdl.handle.net/10902/32626},
abstract = {Magnetic, structural and computational data of four complex salts with the same mononuclear high spin octahedral Mn(III) complex cation are reported. The manifestation of Jahn-Teller-like distortions in the Mn(III) cation is dependent on the nature of the charge-balancing anion, with small anions yielding a planar elongation and large anions freezing out a preferential axial elongation along one of the amine-Mn-imine directions within that same plane. Modulation of the lattice by changing the charge balancing anion results in mixing of the orbital symmetry due to vibrational perturbation.},
publisher = {Royal Society of Chemistry},
publisher = {Dalton Transactions, 2016, 45(15), 6702-6708},
title = {Challenges in assignment of orbital populations in a high spin manganese(III) complex},
author = {Fitzpatrick, Anthony J. and Stepanovic, Stepan and Müller-Bunz, Helge and Gruden, Maja and García Fernández, Pablo (físico) and Morgan, Grace G.},
}