@article{10902/14246, year = {2018}, month = {6}, url = {http://hdl.handle.net/10902/14246}, abstract = {In the present work, the effect of zeolite type and topology on CO2 and N2 permeability using zeolites of different topology (CHA, RHO, and LTA) in the same Si/Al = 5, embedded in poly(trimethylsilyl-1-propyne) (PTMSP) is evaluated with temperature. Several models are compared on the prediction of CO2/N2 separation performance and then the modified Maxwell models are selected. The CO2 and N2 permeabilities through these membranes are predicted with an average absolute relative error (AARE) lower than 0.6% taking into account the temperature and zeolite loading and topology on non-idealities such as membrane rigidification, zeolite-polymer compatibility and sieve pore blockage. The evolution of this structure-performance relationship with temperature has also been predicted.}, organization = {The authors gratefully acknowledge the financial support of the Spanish MINECO—General Secretariat for Research, Development and Innovation under project CTQ2016-76231-C2-1-R at the University of Cantabria, and MAT2015-71842-P, at the Instituto de Tecnología Química.}, publisher = {MDPI AG}, publisher = {Membranes 2018, 8(2), 32}, title = {Estimating CO2/N2 permselectivity through Si/Al = 5 small-pore zeolites/PTMSP mixed matrix membranes: influence of temperature and topology}, author = {Casado Coterillo, Clara and Fernández Barquín, Ana and Valencia Valencia, Susana and Irabien Gulías, Ángel}, }