@phdthesis{10902/14079,
year = {2018},
month = {6},
url = {http://hdl.handle.net/10902/14079},
abstract = {ABSTRACT: This thesis describe the preparation of Ag NP/activator/WPUU and AgBF4/BMImBF4/WPUU membranes for the separation of olefin/paraffin gas mixtures. In this work, two activator compounds were used for Ag NP, pbenzoquinone (p-Bq) and BMImBF4. The discussion of paraffin and olefin mass transport trough membranes is carried out in the same chapter. The facilitated transport of olefin was not achieved in Ag NP/activator/WPUU membranes, probably caused by the low electron acceptor feature of BMImBF4 and by the poor stability of p-Bq. On the other hand, the facilitated transport of olefins was reached in AgBF4/BMImBF4/WPUU membranes. However, the membrane evidenced a humidification dependence to be stable in long-term permeation experiments. Finally, the overall conclusions of the Thesis and challenges for future researches are presented.},
organization = {Antoniel Carlos Campos thanks the Federal Agency for Support and Evaluation of Graduate Education – CAPES (PDSE Grant - 88881.134232/2016-01) and the Spanish Ministry of Economy, Industry and Competitiveness (CTQ2015-66078-R and CTQ2016-75158-R projects, Spain-FEDER 2014-2020) for financial support},
title = {Poly(urethane-urea) composite membranes with Ag NP/activator and AgBF4/BMImBF4 systems for light olefins/paraffins separations},
author = {Carolino Campos, Antoniel Carlos},
}