@article{10902/10542,
year = {2015},
url = {http://hdl.handle.net/10902/10542},
abstract = {The nonoxidizing catalytic noble metal rhodium is introduced for ultraviolet plasmonics. Planar tripods of 8 nm Rh nanoparticles, synthesized by a modified polyol reduction method, have a calculated local surface plasmon resonance near 330 nm. By attaching p-aminothiophenol, local field-enhanced Raman spectra and accelerated photodamage were observed under near-resonant ultraviolet illumination, while charge transfer simultaneously increased fluorescence for up to 13 min. The combined local field enhancement and charge transfer demonstrate essential steps toward plasmonically enhanced ultraviolet photocatalysis.},
organization = {This work has
been supported by NSF-ECCS-12-32239. This work was
partially supported by the Army’s In-house Laboratory
Innovative Research program. Financial support from USAITCA
(project no. W911NF-13-1-0245) and MICINN (Spanish
Ministry of Science and Innovation, project no. FIS2013-
45854-P) is also acknowledged.},
publisher = {ACS Publications},
publisher = {Nano Lett. 2015, 15, 1095−1100},
title = {Rhodium nanoparticles for ultraviolet plasmonics},
author = {Watson, Anne M. and Zhang, Xiao and Alcaraz de la Osa, Rodrigo and Sanz Casado, Juan Marcos and González Fernández, Francisco and Moreno Gracia, Fernando and Finkelstein, Gleb and Liu, Jie and Everitt, Henry O.},
}